STEREOSPECIFIC POLYMERIZATION OF ALPHA-OLEFINS - END GROUPS, POLYMER STRUCTURE AND REACTION-MECHANISM

被引：30

作者：

ZAMBELLI, A

AMMENDOLA, P

机构：

[1] Dipartimento di Fisica, Università di Salerno, I-84081 Baronissi, SA

来源：

PROGRESS IN POLYMER SCIENCE | 1991年 / 16卷 / 2-3期

关键词：

D O I：

10.1016/0079-6700(91)90016-E

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

In this paper are reviewed some topics concerning polymerization of alpha-olefins to either isotactic or syndiotactic polymers in the presence of both heterogeneous and homogeneous initiator systems. Isotactic polymerization of chiral alpha-olefins and isotactic and syndiotactic specific polymerization of styrene are also discussed. The evidence relating to reaction mechanisms which arises from the stereochemical structure of the polymers and especially of the end groups is considered particularly.

引用

页码：203 / 218

页数：16

共 65 条

[1]

ALLEGRA G, 1971, MAKROMOLEKUL CHEM, V145, P235

[2]

AMMENDOLA P, 1988, GAZZ CHIM ITAL, V118, P769

[3] ISOTACTIC POLYMERIZATION OF STYRENE AND VINYLCYCLOHEXANE IN THE PRESENCE OF A C-13-ENRICHED ZIEGLER-NATTA CATALYST - REGIOSELECTIVITY AND ENANTIOSELECTIVITY OF THE INSERTION INTO METAL METHYL BONDS [J].