ETHYLENE DIMERIZATION - AN ALTERNATIVE ROUTE INVOLVING VINYL HYDRIDE INTERMEDIATES

被引：35

作者：

PEREZ, PJ ^{[1
]}

POVEDA, ML ^{[1
]}

CARMONA, E ^{[1
]}

机构：

[1] UNIV SEVILLA,CSIC,INST CIENCIA MAT,DEPT QUIM INORGAN,APDO 553,E-41071 SEVILLE,SPAIN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 01期

关键词：

D O I：

10.1039/c39920000008

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The new complex Tp*Ir(C2H4)2 1 [Tp* = hydrotris(3,5-dimethyl-1-pyrazolyl)borate] rearranges thermally into the hydrido-allyl Tp*Ir(H)(eta(3)-CH2CHCHMe) 2 (cyclohexane, 60-degrees-C, 15 h) through the intermediate vinyl-hydride Tp*Ir(H)(CH = CH2)(C2H4) 3, as demonstrated by an independent synthesis of 3 and its clean conversion into 2.

引用

页码：8 / 9

页数：2

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