AROMATIC NITROGEN BRIDGEHEAD COMPOUNDS .3. SYNTHESIS OF 8A,10A-DIAZONIAPHENANTHRENE AND RELATED CATIONS

被引:13
作者
CALDER, IC
SASSE, WHF
机构
[1] Department of Organic Chemistry, University of Adelaide, Adelaide, 5001
[2] Department of Chemistry, University of Melbourne, Parkville, VIC
[3] Synthetic Chemistry Section, Division of Applied Chemistry, CSIRO, Chatswood, NSW, 2067
关键词
D O I
10.1071/CH9682951
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The acid-induced cyclization of 1-acylmethyl-2-(2-pyridyl)pyridinium salts to 9, 10-dihydro-9-hydroxy-8a, l0a-diazoniaphenanthrene salts, and the reversal of this reaction are described. These salts can be dehydrated to give 8a, l0a-diazoniaphenanthrene salts. 3a, 8a-Diazoniapyrene salts can be made similarly. © 1968 CSIRO. All rights reserved.
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页码:2951 / &
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