NEW FLUOROPALLADATES(II) M2[PDF4] (M = NA,K) AND K2RBPDF5

被引：11

作者：

BACHMANN, B ^{[1
]}

MULLER, BG ^{[1
]}

机构：

[1] UNIV GIESSEN,INST ANORGAN & ANALYT CHEM,HEINRICH BUFF RING 58,W-6300 GIESSEN,GERMANY

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1991年 / 597卷 / 06期

关键词：

ALKALI FLUORO PALLADATE(II); PREPARATION; SINGLE CRYSTAL STRUCTURE;

D O I：

10.1002/zaac.19915970103

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

For the first time bright yellow single crystals M2[PdF4] (M = Na, K) have been obtained and their structure determined. K2[PdF4] crystallizes monoclinic, space group C2/m-C2h3 (No. 12) with a = 975.2(3) pm, b = 597.6(1) pm, c = 420.2(1) pm, beta = 92.17(2)-degrees and Z = 2. Structure related Na2[PdF4] crystallizes monoclinic too, but in space group P2(1)/c-C2h5 (No. 14) with a = 340.88(7) pm, b = 561.1(1) pm, c = 999.2(2) pm, beta = 93.97(2)-degrees and Z = 2. K2RbPdF5, yellow, crystallizes tetragonal with a = 724.9(1) pm, c = 627.9(1) pm, Z = 2 and is isotypic with Rb2CsPdF5 (space group P4/mbm-D4h5, No. 127), an ordered structure variant of the Rb3PdF5-type [1].

引用

页码：9 / 18

页数：10

共 7 条

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[4] THE STRUCTURE OF CAPDF4, CDPDF4, HGPDF4 AND HP-PDF2
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[J]. JOURNAL OF FLUORINE CHEMISTRY, 1982, 20 (03) : 291 - 299
[5] ON COMPLEX FLUORIDES WITH CU-2+ AND PD-2+ - PDPTF6, CUPTF6 AND RBCUPDF5
MULLER, BG
[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1988, 556 (01): : 79 - 84
[6] NEW FLUOROPALLADATES(II)
MULLER, BG
[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1982, 491 (08): : 245 - 252
[7] SHELDRICK GM, 1976, SHELX PROGRAM CRYSTA

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