ASSURING TRUENESS OF ANALYTICAL RESULTS

被引:26
作者
DOERFFEL, K
机构
[1] Department of Chemistry, Geusaer Strasse, Technical University Merseburg, Merseburg
来源
FRESENIUS JOURNAL OF ANALYTICAL CHEMISTRY | 1994年 / 348卷 / 03期
关键词
D O I
10.1007/BF00325357
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
A true analytical result presumes an analytical procedure without systematic errors. They can be detected by comparing the analytical results with the true value or with an accepted reference. Systematic errors are always superimposed by the random error, therefore such a comparison must include statistical tests. The paper describes suitable test-models for typical analytical problems, as e.g. the validation of an analytical procedure or the (current) control of analytical work. Furthermore, explanations will be given for the interpretation of the test results due to the trueness of analytical data and for the consequences concerning analytical work.
引用
收藏
页码:183 / 187
页数:5
相关论文
共 16 条
[1]  
BARNARD GA, 1959, J ROY STAT SOC B, V21, P239
[2]   ROBUST STATISTICS IN ANALYTICAL-CHEMISTRY [J].
DANZER, K .
FRESENIUS ZEITSCHRIFT FUR ANALYTISCHE CHEMIE, 1989, 335 (08) :869-875
[3]  
DATHE K, 1979, SBORNIK VYS SKOLY CH, V14, P233
[4]  
DOERFEL K, 1990, STATISTIK ANAL CHEM
[5]   DETECTION OF SYSTEMATIC-ERRORS BY WEIGHTED REGRESSION [J].
DOERFFEL, K ;
HEBISCH, R .
FRESENIUS ZEITSCHRIFT FUR ANALYTISCHE CHEMIE, 1988, 331 (05) :510-512
[6]   FEHLERRECHNUNG IN DER ANALYTISCHEN CHEMIE .2. DIE SYSTEMATISCHEN FEHLER [J].
DOERFFEL, K .
FRESENIUS ZEITSCHRIFT FUR ANALYTISCHE CHEMIE, 1957, 157 (04) :241-248
[7]  
DOERFFEL K, 1991, FRASENIUS J ANAL CHE, V34, P519
[8]  
GEYER R, 1957, FRESEN Z ANAL CHEM, V158, P419
[9]  
HAUTHAL J, 1973, THESIS MERSEBURG
[10]  
MARSHALL RA, 1979, ANAL CHEM, V49, P2193