A RIETVELD STUDY OF THE CATION SUBSTITUTION BETWEEN UVAROVITE AND YTTRIUM-ALUMINUM SYNTHETIC GARNETS, OBTAINED BY SOL-GEL METHOD

被引：15

作者：

CARDA, J ^{[1
]}

TENA, MA ^{[1
]}

MONROS, G ^{[1
]}

ESTEVE, V ^{[1
]}

REVENTOS, MM ^{[1
]}

AMIGO, JM ^{[1
]}

机构：

[1] UNIV VALENCIA,DEPT GEOL,E-46100 BURJASSOT,SPAIN

来源：

CRYSTAL RESEARCH AND TECHNOLOGY | 1994年 / 29卷 / 03期

关键词：

D O I：

10.1002/crat.2170290320

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

A series of synthetic garnets solid solutions is compositions between Y3Al2Al3O12 (Y-Al garnet) (YAG) and Ca3Cr2Si3O12 (uvarovite) was synthesized using the sol-gel method. The expected general formula is (CaxY1-x)3 (CrxAl-x)2 (SixAl1-x)3O12 where x = 0 to x = 1. The cation distribution in dodecahedral, octahedral and tetrahedral sites and bond distances in these synthetic garnets were determined using the Rietveld method. It shows the incomplete substitution in small sites. The smaller site the smaller substitution there is.

引用

页码：387 / 391

页数：5

共 7 条

[1] SYNTHESIS OF UVAROVITE GARNET [J].