VAPOR-LIQUID EQUILIBRIA OF BINARY SYSTEMS OF METHANOL WITH ANISOLE CHLOROBENZEN NITROMETHANE AND PYRIDINE

被引:15
作者
NAKANISHI, K
SHIRAI, H
NAKASATO, K
机构
[1] Department of Industrial Chemistry, Kyoto University, Kyoto
[2] Department of Industrial Chemistry, Shinshu University, Nagano
[3] Hitachi Seisakusho Co. Ltd, Tokyo
关键词
D O I
10.1021/je60037a013
中图分类号
O414.1 [热力学];
学科分类号
摘要
Vapor-liquid equilibrium data are reported for binary systems of methanol with anisole (PhOMe), chlorobenzene (PhCI), nitromethane (MeNO2), and pyridine at 730 mm. of Hg. Of the four systems studied, only methanol-MeNO2 forms a minimum azeotrope—at 64.4° C., near 95.0 mole % of methanol. The other three systems are nonazeotropic. Limiting values of the activity coefficients of each component in an excess of methanol have been evaluated. © 1968, American Chemical Society. All rights reserved.
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页码:188 / +
页数:1
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