REVERSAL OF THE SELECTIVITY PRINCIPLE IN FREE-RADICAL ADDITIONS TO ALKENES

被引：24

作者：

GIESE, B

MEIXNER, J

机构：

[1] Institut für Organische Chemie und Biochemie, Technischen Hochschule Darmstadt, D-6100

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1979年 / 18卷 / 02期

关键词：

D O I：

10.1002/anie.197901541

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The selectivity of alkenes in radical reactions increases with increasing reactivity, i.e. the most selective alkenes are the most reactive ones. This result could be of interest, say in radical polymerization. Copyright © 1979 by Verlag Chemie, GmbH, Germany

引用

页码：154 / 155

页数：2

共 12 条

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CARONNA, T
CITTERIO, A
GHIRARDINI, M
MINISCI, F
[J]. TETRAHEDRON, 1977, 33 (07) : 793 - 796
[2] NUCLEOPHILIC CHARACTER OF ALKYL RADICALS .16. ABSOLUTE RATE CONSTANTS AND REACTIVITY-SELECTIVITY RELATIONSHIP IN HOMOLYTIC AROMATIC ALKYLATION
CITTERIO, A
MINISCI, F
PORTA, O
SESANA, G
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (24) : 7960 - 7968
[3] FLEMING I, 1976, FRONTIER ORBITALS OR
[4] POLAR EFFECTS IN ADDITION OF ALKYL RADICALS TO OLEFINS
GIESE, B
MEISTER, J
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1977, 16 (03): : 178 - 179
[5] ADDITION OF ALKANES TO OLEFINS - NEW SYNTHETIC METHOD
GIESE, B
MEISTER, J
[J]. CHEMISCHE BERICHTE-RECUEIL, 1977, 110 (07): : 2588 - 2600
[6] REACTIVITY OF ALKENES IN FREE-RADICAL ADDITIONS
GIESE, B
ZWICK, W
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1978, 17 (01): : 66 - 67
[7] BASIS AND LIMITATIONS OF REACTIVITY-SELECTIVITY PRINCIPLE
GIESE, B
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1977, 16 (03): : 125 - 136
[8] GIESE B, 1977, TETRAHEDRON LETT, P2779
[9] GIESE B, 1977, ANGEW CHEM, V89, P162
[10] GIESE B, 1977, ANGEW CHEM, V89, P178

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