COPPER(I) AND SILVER(I) HOMOMETALLIC COMPLEXES OF NEW BIS(2,2'-BIPYRIDINE) LIGANDS

被引：18

作者：

BEER, PD

WHEELER, JW

MOORE, CP

机构：

[1] UNIV BIRMINGHAM,SCH CHEM,BIRMINGHAM B15 2TT,W MIDLANDS,ENGLAND

[2] KODAK LTD,HARROW HA1 4TY,MIDDX,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1992年 / 18期

关键词：

D O I：

10.1039/dt9920002667

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

New ligand systems containing two 2,2'-bipyridin-6-ylmethyl moieties linked via 1,4,10,13-tetraoxa-7,16-diazacyclooctadecane, 1,4,10,13-tetrathia-7,16-diazacyclooctadecane, 4,4'-bipyridinediium, N,N',N"-tritosyldiethylenetriamine and toluene-p-sulfonamide spacer units have been prepared. A variety of homometallic copper(I) complexes have been isolated and fast atom bombardment mass spectrometry investigations suggest most of the complexes to be of general formula [Cu2L2] [PF6]2. Solution H-1 NMR spectra of these species imply the existence of additional complex components of 1:1 L: copper(I) ratio. A variety of mono- and bi-metallic silver(I) complexes were also isolated with these ligands.

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页码：2667 / 2673

页数：7

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