REACTIONS OF 5-ALKOXYOXAZOLES WITH ALDEHYDES IN THE PRESENCE OF LEWIS ACID - REGIOSELECTIVE AND STEREOSELECTIVE FORMATION OF 4-ALKOXYCARBONYL-2-OXAZOLINES

被引:30
作者
SUGA, H
SHI, XL
FUJIEDA, H
IBATA, T
机构
[1] Institute of Chemistry, College of General Education, Osaka University, Toyonaka, Osaka
关键词
D O I
10.1016/0040-4039(91)80442-9
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The [3 + 2] cycloaddition of 5-alkoxyoxazoles with aldehydes in the presence of the organoaluminum reagent, which was prepared from (+/-)-2,2'-dihydroxy-1,1'-dinaphthyl and AlMe3, gave cis-4-alkoxycarbonyl-2-oxazolines in high regio- and stereoselective manner.
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页码:6911 / 6914
页数:4
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