THE EFFECT OF CONTROL FIELD AND MEASUREMENT IMPRECISION ON LABORATORY FEEDBACK-CONTROL OF QUANTUM-SYSTEMS

被引:38
作者
TOTH, GJ [1 ]
LORINCZ, A [1 ]
RABITZ, H [1 ]
机构
[1] PRINCETON UNIV,DEPT CHEM,PRINCETON,NJ 08544
关键词
D O I
10.1063/1.467555
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Recent theoretical studies suggest the feasibility of laboratory adaptive feedback optimal control (AFOC) of chemical processes with the use of ultrashort laser pulses. The feedback process is introduced to provide robustness to laboratory error and electric field design uncertainties. Adaptive approaches for laboratory applications have been suggested. To foster laboratory implementation a number of questions still need to be answered. The paper addresses the problem of AFOC in the presence of laboratory errors and uncertainties both in adjusting the control parameters and in measuring the results. Through simulations we show that there exist optimization methods which are robust against systematic errors and certain optimization methods are also fairly robust against uncertainties. These results suggest that the effect of inevitable laboratory errors can be overcome. Furthermore the results suggest that noise is not a major problem and optimization in the laboratory is feasible.
引用
收藏
页码:3715 / 3722
页数:8
相关论文
共 16 条
[1]   OPTIMAL-CONTROL OF QUANTUM-SYSTEMS BY CHIRPED PULSES [J].
AMSTRUP, B ;
DOLL, JD ;
SAUERBREY, RA ;
SZABO, G ;
LORINCZ, A .
PHYSICAL REVIEW A, 1993, 48 (05) :3830-3836
[2]   CONTROL OF UNIMOLECULAR REACTIONS USING COHERENT-LIGHT [J].
BRUMER, P ;
SHAPIRO, M .
CHEMICAL PHYSICS LETTERS, 1986, 126 (06) :541-546
[3]   OPTIMALLY CONTROLLED QUANTUM MOLECULAR-DYNAMICS - A PERTURBATION FORMULATION AND THE EXISTENCE OF MULTIPLE SOLUTIONS [J].
DEMIRALP, M ;
RABITZ, H .
PHYSICAL REVIEW A, 1993, 47 (02) :809-816
[4]   OPTIMALLY CONTROLLED QUANTUM MOLECULAR-DYNAMICS - THE EFFECT OF NONLINEARITIES ON THE MAGNITUDE AND MULTIPLICITY OF CONTROL-FIELD SOLUTIONS [J].
DEMIRALP, M ;
RABITZ, H .
PHYSICAL REVIEW A, 1993, 47 (02) :831-837
[5]  
Goldberg DE, 1989, GENETIC ALGORITHMS S
[6]   TEACHING LASERS TO CONTROL MOLECULES IN THE PRESENCE OF LABORATORY FIELD UNCERTAINTY AND MEASUREMENT IMPRECISION [J].
GROSS, P ;
NEUHAUSER, D ;
RABITZ, H .
JOURNAL OF CHEMICAL PHYSICS, 1993, 98 (06) :4557-4566
[7]   TEACHING LASERS TO CONTROL MOLECULES [J].
JUDSON, RS ;
RABITZ, H .
PHYSICAL REVIEW LETTERS, 1992, 68 (10) :1500-1503
[8]   WAVEPACKET DANCING - ACHIEVING CHEMICAL SELECTIVITY BY SHAPING LIGHT-PULSES [J].
KOSLOFF, R ;
RICE, SA ;
GASPARD, P ;
TERSIGNI, S ;
TANNOR, DJ .
CHEMICAL PHYSICS, 1989, 139 (01) :201-220
[9]   OPTIMAL-CONTROL OF QUANTUM-MECHANICAL SYSTEMS - EXISTENCE, NUMERICAL APPROXIMATION, AND APPLICATIONS [J].
PEIRCE, AP ;
DAHLEH, MA ;
RABITZ, H .
PHYSICAL REVIEW A, 1988, 37 (12) :4950-4964
[10]  
Press W. H., 2007, NUMERICAL RECIPES