DELAYED SLIP AFTER STEP STRAINS IN HIGHLY ENTANGLED POLYSTYRENE SOLUTIONS

被引:47
作者
ARCHER, LA
CHEN, YL
LARSON, RG
机构
[1] AT&T Bell Laboratories, Murray Hill, New Jersey
关键词
D O I
10.1122/1.550710
中图分类号
O3 [力学];
学科分类号
08 ; 0801 ;
摘要
Apparent slip within a few micrometers of a glass surface is visualized with a microscope using small glass spheres as tracers suspended in a highly entangled 20% solution of polystyrene of molecular weight 8.42 million, confined between glass plates in a plane Couette device. After step shears of 0.5-5 strain units, particles within a few micrometers of each surface move by 70—500/mi, enough to unload more than half of the imposed shear strain at intermediate strains. The slip displacement, when plotted logarithmically against time, show a peculiar “kink” in the vicinity of the “Rouse” time of 100 s, similar to the kink reported for the shear stress. These results show that the peculiar rheological properties reported for highly entangled solutions are produced by an effective slip phenomenon that occurs either at the wall or in a thin disentanglement layer near it. © 1995, The Society of Rheology. All rights reserved.
引用
收藏
页码:519 / 525
页数:7
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