CALORIMETRIC BEHAVIOR OF METHACRYLIC POLYMERS

被引：9

作者：

GRISKEY, RG

HUBBELL, DO

机构：

[1] Chemical Engineering Department, University of Denver, Denver, Colorado

[2] Textile Research Laboratory, Princeton University, Princeton, New Jersey

来源：

JOURNAL OF APPLIED POLYMER SCIENCE | 1968年 / 12卷 / 04期

关键词：

D O I：

10.1002/app.1968.070120420

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Specific heats for poly(methyl methacrylate), poly(diethylaminoethyl methacrylate), poly(cyclohexyl methacrylate), poly(allyl methacrylate), and poly(ethyl acrylate) were measured from 120 to 300°C. with a drop calorimeter. It was found that existing solid‐state theories and equations were unable to correlate the data. The reason advanced was that such theories were developed for crystalline materials, which differed greatly from the amorphous polymers of the present work. A more successful approach was to use a correlation technique originally developed for organic liquids. Copyright © 1968 John Wiley & Sons, Inc.

引用

页码：853 / &

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