CO-II WITH COORDINATION NUMBER 3 - NA4[COO3] - 1ST OXOCOBALTATE(II) WITH AN ISLAND STRUCTURE

被引：4

作者：

BUROW, W

HOPPE, R

机构：

[1] Institut für Anorganische und Analytische Chemie der Universität, Lahn-Giessen, D-6300

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1979年 / 18卷 / 07期

关键词：

D O I：

10.1002/anie.197905421

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

“Cation‐rich” oxides of alkali metals exhibit surprising structural characteristics. The bright red compound Na4[CoO3] now synthesized (Na2O+CoO,Na:Co4.4:1, sealed Co tube 550°C, 20 d under dry argon) contains an “anion” analogous to CO 32−. (Figure Presented.) Copyright © 1979 by Verlag Chemie, GmbH, Germany

引用

页码：542 / 543

页数：2

共 14 条

[1] COORDINATION NUMBER 3 IN COII - NA10[CO4O9], AN OLIGOOXOCOBALTATE(II)
BUROW, W
HOPPE, R
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1979, 18 (01): : 61 - 62
[2] BUROW W, THESIS U GIESSEN
[3] BUROW W, 1979, ANGEW CHEM, V91, P71
[4] Hoppe, 1970, ANGEW CHEM, V82, P7
[5] MADELUNG CONSTANTS
HOPPE, R
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1966, 5 (01) : 95 - &
[6] KNOWLEDGE OF NA4[FEO3]
HOPPE, R
RIECK, H
[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1977, 437 (DEC): : 95 - 104
[7] XENONDIFLUORID, XEF2
HOPPE, R
MATTAUCH, H
RODDER, KM
DAHNE, W
[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1963, 324 (3-4): : 214 - 224
[8] Hoppe R., 1970, ANGEW CHEM INT EDIT, V9, P25, DOI DOI 10.1002/ANIE.197000251
[9] Hoppe R., 1970, ADVANCES FLUORINE CH, V6, P387
[10] Hoppe R., 1966, ANGEW CHEM, V78, P52

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