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NEW MECHANISM FOR THE REACTION OF OZONE WITH OLEFINS

被引：27
作者：
DODGE, MC
ARNTS, RR
机构：
[1] US Environmental Protection Agency, Environmental Sciences Research Laboratory, North Carolina, 27711, Research Triangle Park
来源：
INTERNATIONAL JOURNAL OF CHEMICAL KINETICS | 1979年 / 11卷 / 04期
关键词：
D O I：
10.1002/kin.550110405
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A mechanism for ozone–olefin reactions is developed that is consistent with the recent findings of several investigations. These findings suggest a reaction sequence leading to the production of fewer free radical species than has been assumed in the past. Computer simulations using the new mechanism reproduce experimental results obtained from the ozonolysis of propylene in air. Copyright © 1979 John Wiley & Sons, Inc.
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页码：399 / 410
页数：12
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