MASS SPECTRAL STUDIES OF METAL CHELATES .2. MASS SPECTRA AND APPEARANCE POTENTIALS OF ACETYLACETONATES OF TRIVALENT METALS OF FIRST TRANSITION SERIES

被引:66
作者
BANCROFT, GM
REICHERT, C
WESTMORE, JB
机构
[1] Department of Chemistry, University of Manitoba, Winnipeg, Manitoba
关键词
D O I
10.1021/ic50063a005
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The mass spectra are reported for the tris acetylacetonates of Ti, V, Cr, Mn, Fe, Co, and Al as well as the appearance potentials of M(acac)3+ and M(acac)2+ derived from these compounds. The results are not in agreement with theoretical calculations and electronic spectra of these molecules. © 1968, American Chemical Society. All rights reserved.
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页码:870 / &
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