SELECTIVE REDUCTIONS .45. ASYMMETRIC REDUCTION OF PROCHIRAL KETONES BY ISO-2-METHYL[2-(BENZYLOXY)ETHYL]APOPINOCAMPHEYL]-TERT-BUTYLCHLOROBORANE, ISO-2-ETHYL[2-(BENZYLOXY)ETHYL]APOPINOCAMPHEYL]-TERT-BUTYLCHLOROBORANE, AND [ISO-2-[2-(BENZYLOXY)ETHYL]APOPINOCAMPHEYL]-TERT-BUTYLCHLOROBORANE - EVIDENCE FOR A MAJOR INFLUENCE OF THE STERIC REQUIREMENTS OF THE 2-SUBSTITUENT ON THE EFFICIENCY OF ASYMMETRIC REDUCTION

被引：35

作者：

BROWN, HC ^{[1
]}

RAMACHANDRAN, PV ^{[1
]}

机构：

[1] PURDUE UNIV,RB WETHERILL LABS CHEM,W LAFAYETTE,IN 47907

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1989年 / 54卷 / 19期

关键词：

D O I：

10.1021/jo00280a013

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

引用

页码：4504 / 4511

页数：8

共 21 条

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[2] CHIRAL SYNTHESIS VIA ORGANOBORANES .22. SELECTIVE REDUCTIONS .44. THE EFFECT OF THE STERIC REQUIREMENTS OF THE ALKYL SUBSTITUENT IN ISOPINOCAMPHEYLALKYLCHLOROBORANES FOR THE ASYMMETRIC REDUCTION OF REPRESENTATIVE KETONES
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[3] SELECTIVE REDUCTIONS .40. A CRITICAL-EXAMINATION OF THE RELATIVE EFFECTIVENESS OF VARIOUS REDUCING AGENTS FOR THE ASYMMETRIC REDUCTION OF DIFFERENT CLASSES OF KETONES
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[4] SELECTIVE REDUCTIONS .37. ASYMMETRIC REDUCTION OF PROCHIRAL KETONES WITH B-(3-PINANYL)-9-BORABICYCLO[3.3.1]NONANE
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[5] A CONVENIENT PROCEDURE FOR QUANTITATIVE CONVERSION OF REACTIVE ALCOHOLS AND OLEFINS INTO CORRESPONDING CHLORIDES
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[6] CHIRAL SYNTHESIS VIA ORGANOBORANES .14. SELECTIVE REDUCTIONS .41. DIISOPINOCAMPHEYLCHLOROBORANE, AN EXCEPTIONALLY EFFICIENT CHIRAL REDUCING AGENT
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[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (05) : 1539 - 1546
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[8] ORGANOBORANES .49. AN EXAMINATION OF CONVENIENT PROCEDURES FOR THE GENERATION OF BORANE AND MONOALKYLBORANES AND DIALKYLBORANES FROM LITHIUM BOROHYDRIDE AND MONOALKYLBOROHYDRIDES AND DIALKYLBOROHYDRIDES
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[J]. ORGANOMETALLICS, 1986, 5 (11) : 2303 - 2307
[9] DALE JA, 1969, J ORG CHEM, V34, P1316
[10] ORGANOBORON COMPOUNDS IN ORGANIC-SYNTHESIS .2. ASYMMETRIC REDUCTION OF DIALKYL KETONES WITH (R,R)-2,5-DIMETHYLBOROLANE OR (S,S)-2,5-DIMETHYLBOROLANE
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