PSEUDOROTATION IN TRIGONAL-BIPYRAMIDAL MOLECULES

被引：96

作者：

LAUTERBUR, PC

RAMIREZ, F

机构：

[1] Department of Chemistry, State University of New York, Stony Brook

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1968年 / 90卷 / 24期

关键词：

D O I：

10.1021/ja01026a029

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A systematic geometrical analysis of isomerizations of trigonal-bipyramidal molecules by pseudorotation is presented. The consequences of introducing several types of constraints upon the processes are discussed. © 1968, American Chemical Society. All rights reserved.

引用

收藏

页码：6722 / +

页数：1

相关论文

共 17 条

[1]

[Anonymous], 1965, ADV FLUORINE CHEM

[2] CORRELATION OF RATES OF INTRAMOLECULAR TUNNELING PROCESSES, WITH APPLICATION TO SOME GROUP-V COMPOUNDS [J].

BERRY, RS .

JOURNAL OF CHEMICAL PHYSICS, 1960, 32 (03) :933-938

[3] RING OPENING AND RECLOSURE IN A CYCLIC PHOSPHORANE [J].

GORENSTEIN, D ;

WESTHEIMER, FH .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 1967, 58 (04) :1747-+

[4] DIE STEREOCHEMIE ORGANISCHER DERIVATE DES FUNFUND SECHSBINDIGEN PHOSPHORS .4. ZUR FRAGE DER SYNKOORDINIERUNG VON ABKOMMLINGEN DES VIER- UND SECHSFACH KOORDINIERTEN PHOSPHORS [J].

HELLWINKEL, D .

CHEMISCHE BERICHTE-RECUEIL, 1966, 99 (11) :3668-+

[5] INTRAMOLECULAR EXCHANGE IN PHOSPHORUS PENTAHALIDE MOLECULES [J].

HOLMES, RR ;

DEITERS, RM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1968, 90 (18) :5021-&

[6]

HUDSON RF, 1965, STRUCTURE MECHANISM

[7] INTRAMOLECULAR RACEMIZATION PROCESSES IN PENTACOORDINATE STRUCTURES [J].

MUETTERT.EL .

INORGANIC CHEMISTRY, 1967, 6 (03) :635-&

[8] PENTACO-ORDINATION [J].

MUETTERTIES, EL ;

SCHUNN, RA .

QUARTERLY REVIEWS, 1966, 20 (02) :245-+

[9] INTRAMOLECULAR REARRANGEMENT OF 6-COORDINATE STRUCTURES [J].

MUETTERTIES, EL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1968, 90 (19) :5097-+

[10] STEREOISOMERISM AT PHOSPHORUS IN CYCLIC OXYPHOSPHORANES . REACTION OF PHOSPHONITE AND PHOSPHINITE ESTERS WITH 3-BENZYLIDENE-2,4-PENTANEDIONE [J].

RAMIREZ, F ;

PILOT, JF ;

MADAN, OP ;

SMITH, CP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1968, 90 (05) :1275-&