STEREOCHEMISTRY OF THE DICARBONYLATION OF OLEFINS USING STYRENE AS THE MODEL-COMPOUND

被引：46

作者：

PISANO, C ^{[1
]}

NEFKENS, SCA ^{[1
]}

CONSIGLIO, G ^{[1
]}

机构：

[1] ETH ZENTRUM,DEPT IND & ENGN CHEM,CH-8092 ZURICH,SWITZERLAND

来源：

ORGANOMETALLICS | 1992年 / 11卷 / 05期

关键词：

D O I：

10.1021/om00041a035

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The dicarbonylation reaction of trans-beta-deuteriostyrene to dimethyl 2-phenylbutanedioate and dimethyl 2,5-diphenyl-4-oxoheptanedioate using Pd-(CF3COO)2/2,2'-bipyridine as the catalyst precursor in the presence of 1,4-benzoquinone (i.e., under conditions suitable for the formation of syndiotactic poly(l-phenyl-3-oxotrimethylene)) takes place stereospecifically in a syn fashion. The same stereochemical outcome was found for the dicarbonylation of the same substrate to dimethyl 2-phenylbutanedioate in the presence of (Diop)Pd-(CF3COO)2.

引用

页码：1975 / 1978

页数：4

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