IPTYCENES, CUPPEDOPHANES AND CAPPEDOPHANES

被引：41

作者：

HART, H

机构：

[1] Department of Chemistry, Michigan State University, East Lansing, Michigan

来源：

PURE AND APPLIED CHEMISTRY | 1993年 / 65卷 / 01期

关键词：

D O I：

10.1351/pac199365010027

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Iptycenes are extended triptycenes. They have attractive rigid frameworks, often with intramolecular cavities, and show exceptional thermal stability. The rapid assembly of iptycenes such as 5, 22, 28, 31 and 37, mainly via cycloaddition reactions, is described. Cuppedophanes and cappedophanes are novel cyclophanes that can be quickly constructed via a tandem aryne-nucleophilic addition sequence. Examples whose synthesis and properties are described include 54, 57, 60 and 65-67.

引用

页码：27 / 34

页数：8

共 35 条

[1] ACQUAAH SO, UNPUB
[2] TRITRIPTYCENE - A D3H C62 HYDROCARBON WITH 3 U-SHAPED CAVITIES
BASHIRHASHEMI, A
HART, H
WARD, DL
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (21) : 6675 - 6679
[3] Cadogan J. I. G., 1971, J CHEM SOC B, P602
[4] IPTYCENE SYNTHESIS - A NEW METHOD FOR ATTACHING A 2,3-ANTHRACENE MOIETY TO THE 9,10-POSITIONS OF ANOTHER ANTHRACENE MOIETY - EXCEPTIONAL CONDITIONS FOR A LEWIS ACID-CATALYZED DIELS-ALDER REACTION
CHEN, YS
HART, H
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1989, 54 (11) : 2612 - 2615
[5] CHIU JJS, UNPUB
[6] CLAR E, 1931, CHEM BER, V64, P1676
[7] A ONE-POT SYNTHESIS OF M-TERPHENYLS VIA A 2-ARYNE SEQUENCE
DU, CJF
HART, H
NG, KKD
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1986, 51 (16) : 3162 - 3165
[8] SYNTHESIS OF TRIARYLBENZENES VIA TANDEM ARYNE REACTIONS OF ARYL GRIGNARDS WITH POLYHALOBENZENES
GHOSH, T
HART, H
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1988, 53 (15) : 3555 - 3558
[9] REACTION OF ARYL GRIGNARD-REAGENTS WITH HEXAHALOBENZENES - NOVEL ARENES VIA A MULTIPLE ARYNE SEQUENCE
HARADA, K
HART, H
DU, CJF
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1985, 50 (26) : 5524 - 5528
[10] A NEW SYNTHESIS OF PARA-TERPHENYLS
HART, H
HARADA, K
[J]. TETRAHEDRON LETTERS, 1985, 26 (01) : 29 - 32

← 1 2 3 4 →