THE STABILITY OF POLYPYRROLE ELECTRICAL-CONDUCTIVITY

被引：29

作者：

CHEN, XB

DEVAUX, J

ISSI, JP

BILLAUD, D

机构：

[1] UNIV CATHOLIQUE LOUVAIN,UNITE PHYS & CHIM HAUTS POLYMERES,1 PL CROIX SUD,B-1348 LOUVAIN,BELGIUM

[2] UNIV NANCY 1,CHIM MINERALE APPL LAB,F-54506 VANDOEUVRE NANCY,FRANCE

[3] UNIV CATHOLIQUE LOUVAIN,UNITE PHYSICOCHIM & PHYS MAT,B-1348 LOUVAIN,BELGIUM

来源：

EUROPEAN POLYMER JOURNAL | 1994年 / 30卷 / 07期

关键词：

D O I：

10.1016/0014-3057(94)90008-6

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The decrease of the electrical conductivity in air of both electrochemically and chemically synthesized polypyrroles is studied. This decrease is found to be due to oxidative degradation. It appears to follow a first-order kinetics. The decrease of the conductivity is larger for the chemically synthesized polypyrrole than for the electrochemically synthesized one because of the larger surface area of the polymer particles in the former.

引用

页码：809 / 811

页数：3

共 7 条

[1]

BOCCHI V, 1986, J CHEM SOC CHEM COMM, P148

[2] STRUCTURE, STRENGTH AND ELECTRICAL PERFORMANCE OF CONDUCTING POLYPYRROLES [J].