ELECTROSTATIC ACTIVATION OF HYPERVALENT ORGANO-IODINE COMPOUNDS - BIS(ONIO)-SUBSTITUTED ARYLIODINE(III) SALTS

被引：81

作者：

WEISS, R

SEUBERT, J

机构：

[1] Institut für Organische Chemie, Universität Erlangen-Nürnberg, Erlangen, D-91054

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 08期

关键词：

D O I：

10.1002/anie.199408911

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new class of compounds, for example 2, synthesized from 1 or iodosobenzene, are the title compounds in this article. The oxidation potential of 1 is increased considerably by bis(onio) substitution; thus, these new systems can be used as potent oxidants. Applications include dehydrogenations of monohydrazones to give diazo compounds and of 1,2‐bishydrazones to give alkynes. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：891 / 893

页数：3

共 27 条

[1] ORGANIC POLYVALENT IODINE COMPOUNDS [J].