STRUCTURE OF INTERMEDIATE IN 4-TRICYANOVINYLATION OF 2,6-DIMETHYLANILINE

被引：40

作者：

RAPPOPOR.Z

SHOHAMY, E

机构：

[1] Department of Organic Chemistry, Hebrew University, Jerusalem

来源：

JOURNAL OF THE CHEMICAL SOCIETY B-PHYSICAL ORGANIC | 1969年 / 02期

关键词：

D O I：

10.1039/j29690000077

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The structure of the isolated intermediate from the 4-tricyanovinylation of 2,6-dimethylaniline with tetracyanoethylene has been investigated. Ultraviolet, infrared, nuclear magnetic resonance, and mass spectra and dipole moment measurements as well as chemical evidence have been used. The evidence favours 2,6-dimethyl-4-(1,1,2,2-tetracyanoethyl)aniline (II) rather than the σ-complex (I). The tricyanovinylation mechanism is discussed.

引用

页码：77 / &

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