SEMI-CLASSICAL CALCULATION OF BOUND-STATES IN MULTIDIMENSIONAL SYSTEMS WITH FERMI RESONANCE

被引:146
作者
NOID, DW
KOSZYKOWSKI, ML
MARCUS, RA
机构
[1] SANDIA LABS,LIVERMORE,CA 94550
[2] CALTECH,ARTHUR AMOS NOYES LAB CHEM PHYS,PASADENA,CA 91125
关键词
D O I
10.1063/1.438677
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A method is devised to calculate eigenvalues semiclassically for an anharmonic system whose two unperturbed modes are 2:1 degenerate. For some special states the periodic energy exchange between unperturbed modes is found to be very large. The quantum mechanical wave functions are examined and a correlation with the classical trajectories is described, both for quasiperiodic and the stochastic cases. A method used in the literature for calculating the stochastic limit is tested and found to break down when the present anharmonic system is separable. © 1979 American Institute of Physics.
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页码:2864 / 2873
页数:10
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