ROLE OF ISOTOPIC DIFFERENCES IN DETERMINATION OF MOLECULAR STRUCTURE - A SUPPLEMENTARY NOTE ON STRUCTURE OF ACROLEIN

被引：237

作者：

KUCHITSU, K

FUKUYAMA, T

MORINO, Y

机构：

[1] Department of Chemistry, Faculty of Science, The University of Tokyo, Hongo, TokyoJapan

来源：

JOURNAL OF MOLECULAR STRUCTURE | 1969年 / 4卷 / 01期

关键词：

D O I：

10.1016/0022-2860(69)85027-1

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The discrepancy between the rao and rz structures of acrolein reported in a previous study has been removed by taking into account small isotopic differences in the distances among the carbon and oxygen atoms. The effect of uncertainties in the isotopic differences on the determination of the average structure is examined, and a general method for deriving the best possible structure from electron-diffraction and spectroscopic data is suggested. The rg bond distances in butadiene, acrolein, and glyoxal are compared with one another. © 1969.

引用

页码：41 / &

共 11 条

[1] SECONDARY ISOTOPE EFFECTS ON AMPLITUDES OF MOLECULAR VIBRATIONS [J].