SOME TRIPHENYLPHOSPHINIMINE COMPLEXES OF ZINC, CADMIUM, MERCURY, RHODIUM AND PALLADIUM

被引：24

作者：

ABEL, EW

MUCKLEJOHN, SA

机构：

[1] Department of Chemistry, University of Exeter, Exeter

来源：

INORGANICA CHIMICA ACTA | 1979年 / 37卷 / 01期

关键词：

D O I：

10.1016/S0020-1693(00)95526-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The in situ alcoholysis of Ph3PNSiMe3 in the presence of anhydrous halides of zinc, cadmium and mercury results in the formation of a range of co-ordination complex of triphenylphosphinimine, Ph3PNH (L). The complexes formed were of three types: i) the trans dimers [(MX2L)2], ii) the cyclic dimers [(MX2L2)2]· (CHCl3)2 and iii) the polymeric (M2X2L3)n. Triphenylphosphinimine complexes of rhodium and palladium results from halogen bridge fission in [{PdCl(η-C3H5)}2] and [{Rh(CO)2Cl}2]. © 1979.

引用

页码：107 / 111

页数：5

共 29 条

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