SPATIAL-ANALYSIS AND MAPPING THE ANNUAL MEAN CONCENTRATIONS OF ACIDITY AND MAJOR IONS IN PRECIPITATION OVER THE UNITED-KINGDOM IN 1986

被引:14
作者
WEBSTER, R
CAMPBELL, GW
IRWIN, JG
机构
[1] AFRC Institute of Arable Crops Research, Rothhamsted Experimental Station, Harpenden, AL5 2JQ, Herts
[2] Warren Spring Laboratory, Department of Trade and Industry, Stevenage, SG1 2BX, Herts, Gunnels Wood Road
关键词
D O I
10.1007/BF00399591
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The composition of precipitation is being monitored in collectors sited throughout the United Kingdom. In the first year, 1986, hydrogen ion, nitrate, ammonium and non-marine sulphate were measured in samples from 47 sites and annual mean concentrations determined. Spatial analysis based on Regionalized Variable Theory revealed autocorrelation in all four ions and reasonable bounded models were fitted to the sample variogram of all four. These were then used to estimate values of a fine mesh grid by simple kriging, and the estimates were then contoured. The estimation errors were similarly mapped, and both sets of maps are presented. The maps show that concentrations of these ions are greatest in eastern parts of the country, as expected from consideration of European emissions and weather patterns. For the first time estimation errors were also mapped and show how the network could be improved.
引用
收藏
页码:1 / 17
页数:17
相关论文
共 18 条
[1]  
ApSimon H.M., Kruse M., Bell J.N.B., Ammonia Emissions and their Role in Acid Deposition, Atmospheric Environment, 21, pp. 1939-1946, (1987)
[2]  
Asman W.A.H., Ridder I.F., Reijnders H.F., Slanina J., Influence and Prevention of Bird Droppings in Precipitation Chemistry Experiments, Water, Air and Soil Pollution, 17, pp. 415-420, (1982)
[3]  
Bilonick R.A., The Space-Time Distribution of Sulphate Deposition in the Northeastern United States, Atmospheric Environment, 19, pp. 1829-1845, (1985)
[4]  
Campbell G.W., Cocksedge J.L., Coster S.M., Dennis A.L., Devenish M., Heyes C.J., Perrin D.A., Stone B.H., Irwin J.G., Acid Rain in the United Kingdom: Spatial Distributions and Seasonal Variations in 1986, (1988)
[5]  
Clarke P.A., Simple Estimates of Wet Removal Timescales of Highly Soluble Gases with Particular Reference to HCL, (1985)
[6]  
Devenish M., The United Kingdom Precipitation Composition Monitoring Networks, (1986)
[7]  
Fowler D., Cape J.N., Leith I.D., Paterson I.S., Kinnaird J.W., Nicholson I.A., Rainfall Acidity in Northern Britain, Nature, London, 297, pp. 383-386, (1982)
[8]  
Guertin K., Villeneuve J-P., Deschenes S., Jacques G., The Choice of Working Variables in the Geostatistical Estimation of the Spatial Distribution of Ion Concentration from Acid Precipitation, Atmospheric Environment, 22, pp. 2787-2801, (1988)
[9]  
Hall D.J., The Precipitation Collector for Use in the Secondary National Acid Deposition Networks, (1986)
[10]  
Heyes C.J., Irwin J.G., Barrett C.F., Acid Deposition Monitoring Networks in the United Kingdon, Advancements in Air Pollution Monitoring Equipment and Procedures, Freiburg im Breisgau, June 1985, pp. 155-168, (1985)