INTRAMOLECULAR OXIDATIVE COUPLING OF AROMATIC-COMPOUNDS .2. THE SYNTHESIS OF (2RS,3SR),2,3-DIMETHYL-1,4-BIS(3,4,5-TRIMETHOXYPHENYL)BUTAN-1-ONE AND (2RS,3RS)-2,3-DIMETHYL-1,4-BIS(3,4,5-TRIMETHOXYPHENYL)BUTAN-1-ONE AND THE DETERMINATION OF STEREOCHEMISTRY

被引：8

作者：

KRAUSS, AS

TAYLOR, WC

机构：

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 1991年 / 44卷 / 09期

关键词：

D O I：

10.1071/CH9911335

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The C-methylation of 3-methyl-1,4-bis(3,4,5-trimethoxyphenyl)butan-1-one (9) gave in a ratio of 4:1 the diastereoisomers, (2RS,3SR)- and (2RS,3RS)-2,3-dimethyl-1,4-bis(3,4,5-trimethoxyphenyl)butan-1-one, (7) and (8) respectively. The stereochemistry of each isomer was determined by conversion into an aryltetralin of known stereochemistry.

引用

页码：1335 / 1340

页数：6

共 4 条

[1] SYNTHESIS OF (+/-)-DEOXYSCHIZANDRIN [J].