HYDRIDOTETRAKIS(TRIPHENYLPHOSPHINE)RHODIUM(I) AS AN EFFECTIVE CATALYST FOR THE REGIOSPECIFIC HYDROSILATION OF ALPHA,BETA-UNSATURATED CARBONYL-COMPOUNDS
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作者:
CHAN, TH
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机构:Department of Chemistry, McGill University, Montreal, Que. H3A 2K6
CHAN, TH
ZHENG, GZ
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机构:Department of Chemistry, McGill University, Montreal, Que. H3A 2K6
ZHENG, GZ
机构:
[1] Department of Chemistry, McGill University, Montreal, Que. H3A 2K6
Hydridotetrakis(triphenylphosphine)rhodium(I) acts as an effective catalyst for the reactions of alpha,beta-unsaturated carbonyl compounds with silanes to give regioselectively the enol silyl ethers in a 1,4-hydrosilation.