EASY DOUBLE METALATION OF A DIPHOSPHINOMETHANE LIGAND - STRUCTURE OF THE REMARKABLE OCTAGOLD CAGE COMPLEX [AU8CL2(MU-3-(MEO)2PCHP(OME)2)2-(MU-4(MEO)2PCP(OME)2)2].CHCL3

被引：13

作者：

PAYNE, NC

RAMACHANDRAN, R

TREURNICHT, I

PUDDEPHATT, RJ

机构：

[1] Department of Chemistry, University of Western Ontario, London, Ontario

来源：

ORGANOMETALLICS | 1990年 / 9卷 / 03期

关键词：

D O I：

10.1021/om00117a062

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of AuCC-t-Bu with (MeO)2PCH2P-(OMe)2 (dmopm), followed by recrystallization first from CH2Cl2 and then from CHCl3, gave the title cage complex, which contains four fused nine-membered rings and the first structurally characterized example of a [μ4-R2PCPR2]2- ligand, formed by easy deprotonation of dmopm. © 1990, American Chemical Society. All rights reserved.

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页码：880 / 882

页数：3

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