NEW TELLUROMETALATES OF GALLIUM AND INDIUM - K[K([18]CROWN-6)](2)[GATE3]CENTER-DOT 2CH(3)CN AND [(NET(4))(5)][IN3TE7]CENTER-DOT-O.5ET(2)O

被引：34

作者：

PARK, CW

SALM, RJ

IBERS, JA

机构：

[1] Department of Chemistry, Northwestern University Evanston, Evanston, Illinois

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 17期

关键词：

GALLIUM COMPOUNDS; INDIUM COMPOUNDS; METALATES; TELLURIUM COMPOUNDS; ZINTL PHASES;

D O I：

10.1002/anie.199518791

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The tellurometalate ions [GaTe3]3− and [In3Te7]5− have been prepared by chemical reduction of Ga2Te3 and In2 Te3, respectively, by potassium in liquid NH3 in the presence of an encapsulating ligand. The [GaTe3]3− ion is essentially trigonal planar; the [In3Te7]5− ion is cuboidal, where one corner is missing (structure shown on the right). These anions have no counterparts in S or Se chemistry. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：1879 / 1880

页数：2

共 33 条

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