DIELS-ALDER REACTIONS IN BETA-CYCLODEXTRIN CAVITIES - A MOLECULAR MODELING STUDY

被引：21

作者：

ALVIRA, E

CATIVIELA, C

GARCIA, JI

MAYORAL, JA

机构：

[1] UNIV ZARAGOZA,FAC CIENCIAS,CSIC,INST CIENCIA MAT ARAGON,DEPT QUIM ORGAN,E-50009 ZARAGOZA,SPAIN

[2] UNIV LA LAGUNA,DEPT FIS FUNDAMENTAL & EXPTL,E-38203 LA LAGUNA,SPAIN

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 12期

关键词：

D O I：

10.1016/0040-4039(95)00193-G

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The catalytic effect of the beta-cyclodextrin on a series of Diels-Alder reactions is explained by means of a molecular model including the calculated transition structures, their interaction with the cyclodextrin and the solvation energies of the reagents. The anomalous behaviour of the diethyl maleate is also explained on the basis of this model.

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页码：2129 / 2132

页数：4

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