SYNTHESES OF HOMOPROAPORPHINES BY PHENOLIC OXIDATIVE COUPLING .2. SEPARATION OF 2 ISOMERIC DIENONES OF HOMOPROAPORPHINES

被引:72
作者
KAMETANI, T
SATOH, F
YAGI, H
FUKUMOTO, K
机构
[1] Pharmaceutical Institute, School of Medicine, Tohoku University, Kitayobancho, Sendai
关键词
D O I
10.1021/jo01266a046
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Oxidation of 1,2,3,4-tetrahydro-7-hydroxy-1-(4-hydroxy-3-methoxyphenethyl)-6-methoxy-2-methylisoquinoline (3) with potassium ferrieyanide or ferric chloride gave a mixture of two isomeric dienones (5a and 5b) which were separated. The methoxy analog of phenethylisoquinoline (4) also gave the dienone 6 by phenolic oxidative coupling reaction. © 1968, American Chemical Society. All rights reserved.
引用
收藏
页码:690 / &
相关论文
共 23 条