HOMOLYTIC AROMATIC SUBSTITUTION BY HETEROCYCLIC FREE RADICALS .3. 3-BENZO[B]THIENYL RADICALS

被引：13

作者：

BENATI, L

MARTELLI, G

SPAGNOLO, P

TIACCO, M

机构：

[1] Istituto di Chimica Organica e di Chimica Industriale dell'Università, Bologna, Viale Risorgimento

来源：

JOURNAL OF THE CHEMICAL SOCIETY B-PHYSICAL ORGANIC | 1969年 / 04期

关键词：

D O I：

10.1039/j29690000472

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reactions of 3-benzo[b]thienyl radicals, generated by the photolysis of 3-iodobenzo[b]thiophen, have been studied in a variety of monosubstituted benzenes as solvents. The isomer ratios, and the relative rates of 3-benzo-thienylation of anisole, cumene, and methyl benzoate have been determined. These values indicate that the 3-benzo[b]thienyl radical has a reactivity intermediate between those of 2- and 3-thienyl radicals. A number of new monosubstituted 3-phenylbenzo[b]thiophens are described.

引用

页码：472 / &

共 14 条

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[10] HOMOLYTIC AROMATIC SUBSTITUTION BY HETEROCYCLIC FREE RADICALS .2. 3-THIENYL RADICALS
MARTELLI, G
SPAGNOLO, P
TIECCO, M
[J]. JOURNAL OF THE CHEMICAL SOCIETY B-PHYSICAL ORGANIC, 1968, (08): : 901 - &

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