2-PHOTON RESONANCE IONIZATION SPECTROSCOPY OF OH/OD-D 2-SIGMA-

被引：16

作者：

COLLARD, M ^{[1
]}

KERWIN, P ^{[1
]}

HODGSON, A ^{[1
]}

机构：

[1] UNIV LIVERPOOL,DEPT CHEM,LIVERPOOL L69 3BX,ENGLAND

来源：

CHEMICAL PHYSICS LETTERS | 1991年 / 179卷 / 5-6期

关键词：

D O I：

10.1016/0009-2614(91)87080-U

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Two-photon resonant multiphoton ionisation spectroscopy between 236 and 248 nm has been used to study the lowest D 2-SIGMA-Rydberg state of the OH/OD radical. The origin bands for OH/OD have been observed and show strong unperturbed rotational structure, offering a sensitive detection technique for OH/OD radicals. The first vibrational level of D 2-SIGMA- has also been seen for OH, allowing the vibrational spacing of the upper state to be determined accurately.

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页码：422 / 428

页数：7

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