TRANSITION-METAL ACTIVATED ORGANIC-COMPOUNDS .35. METHYLATING REDUCTIVE DIMERIZATION OF AROMATIC CARBONYL-COMPOUNDS, A NOVEL ORGANOMETALLIC REACTION

被引：5

作者：

KAUFFMANN, T

JORDAN, J

VOSS, KU

机构：

[1] Organisch-Chemisches Institut, Universität Münster, W-4400

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1991年 / 30卷 / 09期

关键词：

D O I：

10.1002/anie.199111381

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel reaction related to the McMurry reaction, the coupling of aromatic aldehydes and ketones according to Equation (a), is found to take place after methylation of the WV complexes 1 with methyllithium. The yields of 2 are 76–90% (five examples); the reaction does not take place with aliphatic aldehydes and ketones. (Figure Presented.) Copyright © 1991 by VCH Verlagsgesellschaft mbH, Germany

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页码：1138 / 1139

页数：2

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