STRUCTURE AND MECHANICAL-PROPERTIES OF HIGHLY ORIENTED POLY(ETHYLENE-TEREPHTHALATE) FILMS

被引:16
作者
EVSTATIEV, M [1 ]
FAKIROV, S [1 ]
APOSTOLOV, A [1 ]
HRISTOV, H [1 ]
SCHULTZ, JM [1 ]
机构
[1] UNIV DELAWARE,MAT SCI PROGRAM,NEWARK,DE 19716
关键词
D O I
10.1002/pen.760321408
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The relationships between the supermolecular structure of poly(ethylene terephthalate) films subjected to cold drawing and subsequent zone annealing and their mechanical properties are investigated. The effectiveness of zone annealing is compared to that of annealing with fixed ends. Microstructural changes occurring during heat treatment and zone annealing are monitored using wide angle X-ray scattering, small angle X-ray scattering, infrared spectroscopy, differential scanning calorimetry, and static mechanical tests. The very high modulus and strength of the zone-annealed films are directly attributed to the large number of the molecules connecting the crystallites.
引用
收藏
页码:964 / 970
页数:7
相关论文
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