SULFONATES - A NOVEL CLASS OF ORGANIC SULFUR-COMPOUNDS IN MARINE-SEDIMENTS

被引：138

作者：

VAIRAVAMURTHY, A ^{[1
]}

ZHOU, WQ ^{[1
]}

EGLINTON, T ^{[1
]}

MANOWITZ, B ^{[1
]}

机构：

[1] WOODS HOLE OCEANOG INST,DEPT MARINE CHEM & GEOCHEM,WOODS HOLE,MA 02543

来源：

GEOCHIMICA ET COSMOCHIMICA ACTA | 1994年 / 58卷 / 21期

关键词：

D O I：

10.1016/0016-7037(94)90200-3

中图分类号：

P3 [地球物理学]; P59 [地球化学];

学科分类号：

0708 ; 070902 ;

摘要：

X-ray absorption near-edge structure spectroscopy (XANES) used to measure sulfur speciation in a variety of organic-rich marine sediments has established sulfonates as a novel and major component of sedimentary organic sulfur. The origins of sulfonates in sediments are not clear, although both biological and geochemical mechanisms are possible. The accumulation of oxidized sulfonate sulfur in reducing marine sediments was not known previously; hence, a new perspective in sulfur geochemistry is established.

引用

页码：4681 / 4687

页数：7

共 40 条

[1] SULFUR DIAGENESIS IN EVERGLADES PEAT AND ORIGIN OF PYRITE IN COAL [J].

ALTSCHULER, ZS ;

SCHNEPFE, MM ;

SILBER, CC ;

SIMON, FO .

SCIENCE, 1983, 221 (4607) :221-227

[2] IDENTIFICATION OF SULFO-LIPIDS IN NON-PHOTOSYNTHETIC DIATOM NITZSCHIA-ALBA [J].

ANDERSON, R ;

KATES, M ;

VOLCANI, BE .

BIOCHIMICA ET BIOPHYSICA ACTA, 1978, 528 (01) :89-106

[3]

BENSON AA, 1963, ADV LIPID RES, V1, P387

[4] ISOPRENOID THIOPHENES - NOVEL PRODUCTS OF SEDIMENT DIAGENESIS [J].

BRASSELL, SC ;

LEWIS, CA ;

DELEEUW, JW ;

DELANGE, F ;

DAMSTE, JSS .

NATURE, 1986, 320 (6058) :160-162

[5] ORIGINS OF SULFUR IN COAL - IMPORTANCE OF ESTER SULFATE CONTENT OF PEAT [J].

CASAGRANDE, D ;

SIEFERT, K .

SCIENCE, 1977, 195 (4279) :675-676

[6]

DAMSTE JSS, 1990, ORG GEOCHEM, V16, P1077

[7]

EGLINTON TI, 1994, IN PRESS ORG GEOCHEM

[8] A LARGE RESERVOIR OF SULFATE AND SULFONATE RESIDES WITHIN PLASMA-CELLS FROM ASCIDIA-CERATODES, REVEALED BY X-RAY ABSORPTION NEAR-EDGE STRUCTURE SPECTROSCOPY [J].

FRANK, P ;

HEDMAN, B ;

CARLSON, RMK ;

TYSON, TA ;

ROE, AL ;

HODGSON, KO .

BIOCHEMISTRY, 1987, 26 (16) :4975-4979

[9] SULFUR K-EDGE X-RAY ABSORPTION-SPECTROSCOPY OF PETROLEUM ASPHALTENES AND MODEL COMPOUNDS [J].

GEORGE, GN ;

GORBATY, ML .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (09) :3182-3186

[10]

GODCHAUX W, 1984, J BIOL CHEM, V259, P2982

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