METAL-CATALYZED DECARBONYLATION OF PRIMARY ALDEHYDES AT ROOM-TEMPERATURE

被引：70

作者：

OCONNOR, JM

MA, J

机构：

[1] Department of Chemistry (216), University of Nevada at Reno, Reno

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1992年 / 57卷 / 19期

关键词：

D O I：

10.1021/jo00045a015

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The metal-catalyzed decarbonylation of primary aldehydes has been achieved at room temperature in THF solvent by utilization of catalytic amounts of Rh(PPh3)3Cl (2, 5 mol %), in conjunction with stoichio-metric amounts of diphenylphosphoryl azide (DPPA, 4).

引用

页码：5075 / 5077

页数：3

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