CAROS ACID - MOLECULAR-STRUCTURE AND ASSOCIATION IN THE SOLID-STATE AT-130-DEGREES-C

被引：8

作者：

FRANK, W ^{[1
]}

BERTSCHFRANK, B ^{[1
]}

机构：

[1] DEGUSSA AG,FORSCH ANORGAN CHEM,W-6450 HANAU 1,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1992年 / 31卷 / 04期

关键词：

D O I：

10.1002/anie.199204361

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The controlled reaction of concentrated H2O2 with oleum affords H2SO5/H2SO4 mixtures from which single crystals of H2SO5 (1) precipitate The X-ray crystal structure analysis contradicts the postulates based on vibrational spectroscopy and shows that 1 occurs as peroxoacid without intramolecular hydrogen bonds (picture right). but is linked in a layer type structure by strong intermolecular O-H...O hydrogen bonds.

引用

页码：436 / 437

页数：2

共 14 条

[1] Synthesis and formula of Caro's acid (monosulfuric acid) [J].