ENANTIOSELECTIVE EPOXIDATION BY AN OPTICALLY-ACTIVE HYDROPEROXIDE

被引：24

作者：

HAMANN, HJ ^{[1
]}

HOFT, E ^{[1
]}

CHMIELEWSKI, M ^{[1
]}

MACIEJEWSKI, S ^{[1
]}

机构：

[1] POLISH ACAD SCI,INST ORGAN CHEM,WARSAW 42,POLAND

来源：

CHIRALITY | 1993年 / 5卷 / 05期

关键词：

ASYMMETRIC INDUCTION; CAPILLARY GAS CHROMATOGRAPHY; CYCLODEXTRIN STATIONARY PHASES;

D O I：

10.1002/chir.530050511

中图分类号：

R914 [药物化学];

学科分类号：

100701 ;

摘要：

Enantioselective epoxidation of prochiral allylic alcohols with optically active 4,6-di-O-acetyl-2,3-dideoxy-alpha-D-threo-hex-2-enopyranosyl hydroperoxide in the presence of Ti(O-i-Pr)4 gives chiral epoxy alcohols with moderate enantiomeric excess. (C) 1993 Wiley-Liss, Inc.

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页码：338 / 340

页数：3

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