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HIGHLY FLUORINATED FULLERENES AS OXIDIZERS AND FLUORINATING AGENTS

被引：32
作者：
GAKH, AA
TUINMAN, AA
ADCOCK, JL
COMPTON, RN
机构：
[1] UNIV TENNESSEE,DEPT CHEM,KNOXVILLE,TN 37996
[2] OAK RIDGE NATL LAB,OAK RIDGE,TN 37831
来源：
TETRAHEDRON LETTERS | 1993年 / 34卷 / 45期
关键词：
D O I：
10.1016/S0040-4039(00)79278-1
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Contrary to the chemistry of ''standard'' fluorocarbons, highly fluorinated fullerenes (C60F44 - C60F46) display distinct oxidizing and fluorinating properties. They liberate iodine from NaI solutions, oxidize isopropanol to acetone, and fluorinate aromatic compounds in the presence of acid catalysts such as BF3.Et2O. Fluoroaromatic products are also generated in the reaction of these fluorofullerenes with organolithium reagents. Even the relatively unreactive heterocycle pyridine is fluorinated by the higher fluorofullerenes. Reaction mechanisms are proposed to explain these observations.
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页码：7167 / 7170
页数：4
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