TRANSANNULAR ADDITION OF METHYLLITHIUM TO 5,12/6,11-DI[1,2]BENZENODIBENZO[A,E]CYCLOOCTENE AND ITS 5,6-EPOXY DERIVATIVE

被引：16

作者：

HERGES, R

NEUMANN, H

HAMPEL, F

机构：

[1] Institut Für Organische Chemie, Universität Erlangen-Nürnberg, Erlangen, D-91054

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1994年 / 33卷 / 09期

关键词：

D O I：

10.1002/anie.199409931

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Deviations from the usual reaction pattern of strained olefins and epoxides occur in the reactions of the title compounds with methyllithium. Thus, for example, the indene derivative 2 forms in a nucleophilic, transannular homo‐1,4‐addition from 1; an analogous transannular substitution takes place for its epoxide. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

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页码：993 / 995

页数：3

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