AN E1CB MECHANISM FOR THE ALKALINE-HYDROLYSIS OF THIOLESTERS OF FLUORENE-9-CARBOXYLIC ACID - EFFECT OF ESTER CONJUGATE BASE STRUCTURE ON DIFFERENTIAL ELIMINATIVE REACTIVITY OF OXYGEN AND SULFUR NUCLEOFUGES

被引：4

作者：

ALBORZ, M ^{[1
]}

DOUGLAS, KT ^{[1
]}

SAID, FM ^{[1
]}

机构：

[1] UNIV ESSEX,DEPT CHEM,COLCHESTER CO4 3SQ,ESSEX,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 1982年 / 11期

关键词：

D O I：

10.1039/p29820001467

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

引用

页码：1467 / 1470

页数：4

共 11 条

[1] EFFECT OF AN AROMATIC ESTER CONJUGATE BASE ON E1CB ESTER HYDROLYSIS - ALKALINE-HYDROLYSIS OF FLUORENE-9-CARBOXYLATE ESTERS
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[2] A MECHANISTIC CHANGE IN THE ALKALINE-HYDROLYSIS OF ESTERS OF FLUORENE-9-CARBOXYLIC ACID
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[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1980, (15) : 728 - 730
[3] THERMODYNAMIC ACID DISSOCIATION-CONSTANTS OF AROMATIC THIOLS
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[4] LEAVING GROUP EFFECTS IN THIOLESTER ALKALINE-HYDROLYSIS .1. A KETEN-MEDIATED (E1CB) PATHWAY FOR BASIC HYDROLYSIS OF S-ACETOACETYLCOENZYME-A AND ANALOGS
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[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1980, (07): : 1037 - 1044
[5] LEAVING GROUP EFFECTS IN THIOLESTER HYDROLYSIS .2. ON THE POSSIBILITY OF AN ELIMINATION-ADDITION (KETEN) MEDIATED PATHWAY IN S-ACETYLCOENZYME-A BASIC HYDROLYSIS AND ACETYL TRANSFER
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[6] AN UNUSUAL ELIMINATION ADDITION (KETEN-MEDIATED) AMINOLYSIS PATHWAY FOR MALONIC S-THIOESTERS, INCLUDING S-MALONYL COENZYME-A
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[7] DOUGLAS KT, 1976, PROGR BIOORGANIC CHE, V4, P193
[8] ELIMINATION AND ADDITION-REACTIONS .30. LEAVING GROUP ABILITIES IN ALKENE-FORMING ELIMINATIONS ACTIVATED BY SULFONYL GROUPS
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THOMAS, PJ
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[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1977, (14): : 1898 - 1909
[9] CARBANION MECHANISM (E1CB) OF ESTER HYDROLYSIS .3. SOME STRUCTURE-REACTIVITY STUDIES AND KETENE INTERMEDIATE
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[10] PRICE CC, 1964, J AM CHEM SOC, V68, P498

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