THE GROTTHUSS MECHANISM

被引：2870

作者：

AGMON, N ^{[1
]}

机构：

[1] HEBREW UNIV JERUSALEM,FRITZ HABER RES CTR,IL-91904 JERUSALEM,ISRAEL

来源：

CHEMICAL PHYSICS LETTERS | 1995年 / 244卷 / 5-6期

基金：

以色列科学基金会;

关键词：

D O I：

10.1016/0009-2614(95)00905-J

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Suggested mechanisms for proton mobility are confronted with experimental findings and quantum mechanical calculations, indicating that no model is consistent with the existing data. It is suggested that the molecular mechanism behind prototropic mobility involves a periodic series of isomerizations between H9O4+ and H5O2+, the first triggered by hydrogen-bond cleavage of a second-shell water molecule and the second by the reverse, hydrogen-bond formation process.

引用

页码：456 / 462

页数：7

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