STEREOCHEMISTRY OF BICYCLO[3.2.1]OCTANE .16. ALLYLIC REACTIVITY OF BICYCLO[3.2.1]OCTENE-2 - REDUCTION WITH METAL HYDRIDES

被引：15

作者：

JEFFORD, CW

MAHAJAN, SN

GUNSHER, J

机构：

[1] Department of Chemistry, Temple University, Philadelphia

来源：

TETRAHEDRON | 1968年 / 24卷 / 07期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/S0040-4020(01)98700-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reductive debromination of exo-1-methyl-3,4-dibromobicyclo[3.2.1]octene-2 and its allylic isomer with LAH and LAD was shown to take place by an SN2′ mechanism. Moreover, it was established that the entering deuteride and leaving bromide ions were cis to each other. © 1968.

引用

页码：2921 / +

页数：1

共 30 条

[1]

BENTLEY KW, 1965, ISOQUINOLINE ALKALOI, P112

[2] STRUCTURAL EFFECTS IN SOLVOLYTIC REACTIONS .I. ROLE OF EQUILIBRATING CATIONS IN CARBONIUM ION CHEMISTRY . NATURE OF INTERMEDIATES INVOLVED IN SOLVOLYSIS OF SYMMETRICALLY SUBSTITUTED BETA-PHENYLETHYL DERIVATIVES [J].