LIGAND POLARIZATION AND TRANSFERRED HYPERFINE INTERACTIONS

被引：6

作者：

ADAM, CD ^{[1
]}

HARKER, AH ^{[1
]}

OWEN, J ^{[1
]}

机构：

[1] AERE,DIV THEORET PHYS,HARWELL OX11 0RA,OXFORDSHIRE,ENGLAND

来源：

JOURNAL OF PHYSICS C-SOLID STATE PHYSICS | 1979年 / 12卷 / 06期

关键词：

D O I：

10.1088/0022-3719/12/6/006

中图分类号：

O469 [凝聚态物理学];

学科分类号：

070205 ;

摘要：

Recent ENDOR measurements of transferred hyperfine interactions in the linear structure M3+-F--Cd2+, where M 3+=Fe3+ or Cr3+ and the host lattice is CsCdF3, have given anomalous results when interpreted by standard ligand hyperfine structure theory. The data have therefore been reinterpreted allowing for polarisation of the F- ligand by the electric field from its neighbours. This is found to improve agreement between theory and experiment, especially if the fluoride ion is allowed to relax towards the M3+ ion, but some difficulties still remain.

引用

页码：L239 / L241

页数：3

共 9 条

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