KINETICS AND MECHANISM OF DIMETHYLCADMIUM AUTOOXIDATION IN DECANE

被引：5

作者：

ALEXANDROV, YA ^{[1
]}

LEBEDEV, SA ^{[1
]}

KUZNETSOVA, NV ^{[1
]}

RAZUVAEV, GA ^{[1
]}

机构：

[1] ACAD SCI USSR,INST CHEM,GORKI,USSR

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 177卷 / 01期

关键词：

D O I：

10.1016/S0022-328X(00)92334-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The liquid-phase auto-oxidation of dimethylcadmium in n-decane has been investigated at 45-60°C. The process occurs by a chain free-radical mechanism, to give the auto-oxidation products MeOOCdMe and (MeOO)2Cd. The chain-initiation reaction has been studied by the inhibitor method. The rate of radical generation decreases with increasing oxygen concentration in the reaction mixture. The role of peroxide products in the auto-oxidation process has been clarified, and the probable mechanism of dimethylcadmium auto-oxidation is discussed. © 1979.

引用

页码：91 / 99

页数：9

共 12 条

[1] FORMATION OF A REVERSIBLE COMPLEX BETWEEN DIETHYLCADMIUM AND OXYGEN [J].

ALEXANDR.YA ;

FIGUROVA, GN ;

RAZUVAEV, GA .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1973, 57 (01) :71-75

[2]

ALEXANDROV YA, 1978, ZHIDKOFAZNOE AVTOOKI, P41

[3]

ALEXANDROV YA, 1978, ZN ORG KHIM, V48, P1660

[4]

ALEXANDROV YA, 1978, ZH ORG KHIM, V48, P1659

[5]

BARYSHNIKOV YN, 1973, T KHIM KHIM TEKHNOL, V2, P33

[6]

BRILKINA TG, 1966, REAKTSII METALLOORGA, P247

[7]

EMANUEL IM, 1965, TSEPNYE REAKTSII OKI, P275

[8]

INGOLD K, 1974, REAKTSII SVOBODNORAD, P11

[9]

PRSHIBL R, 1960, KOMPLEKSONY KHIMICHE, P310

[10]

REUTOV OA, 1972, MEKHANIZMY REAKTSII, P39

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