DIELS-ALDER REACTIONS OF P-CHLORO (BISTRIMETHYLSILYL) METHYLENE PHOSPHINE

被引：15

作者：

ABBARI, M

COSQUER, P

TONNARD, F

KO, YYCYL

CARRIE, R

机构：

[1] UNIV RENNES 1,RECH PHYSICOCHIM STRUCT GRP,CNRS,URA 704,AVE GEN LECLERC,F-35042 RENNES,FRANCE

[2] UNIV RENNES 1,DEPT PHYS CRISTALLINE,CNRS,URA 804,F-35042 RENNES,FRANCE

来源：

TETRAHEDRON | 1991年 / 47卷 / 01期

关键词：

D O I：

10.1016/0040-4020(91)80009-Q

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The electrophilic dienophile, P-chloro (bistrimethylsilyl) methylene phosphine reacts with electron poor or rich dienes to give the [47π + 2π] cycloadducts whose structures are determined by NMR. The regiospecificity of the reaction is satisfactorily predicted by the second order perturbation theory. © 1991.

引用

页码：71 / 82

页数：12

共 64 条

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