THE FIRST ORGANIC CATION-RADICAL SALT SUPERCONDUCTOR (T-C=4K) WITH AN ORGANOMETALLIC ANION - SUPERCONDUCTIVITY, SYNTHESIS AND STRUCTURE OF K-L-(BEDT-TTF)(2)CU(CF3)(4)CENTER-DOT-TCE

被引：42

作者：

SCHLUETER, JA

GEISER, U

WILLIAMS, JM

WANG, HH

KWOK, WK

FENDRICH, JA

CARLSON, KD

ACHENBACH, CA

DUDEK, JD

NAUMANN, D

ROY, T

SCHIRBER, JE

BAYLESS, WR

机构：

[1] ARGONNE NATL LAB,DIV CHEM & MAT SCI,ARGONNE,IL 60439

[2] UNIV COLOGNE,INST ANORGAN CHEM,D-50939 COLOGNE,GERMANY

[3] SANDIA NATL LABS,ALBUQUERQUE,NM 87185

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 13期

关键词：

D O I：

10.1039/c39940001599

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Superconductivity at ambient pressure with onset T-c = 4.00 +/- 0.05 K is reported in a unique organic cation-radical salt K-L-(ET)(2)Cu(CF3)(4).TCE, [ET = bis(ethylenedithio)tetrathiafulvalene, TCE = 1,1,2-trichloroethane] with the Cu(CF3)(4)(-) species being the first Cu3+ and F containing organometallic anion in an organic superconductor.

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页码：1599 / 1600

页数：2

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